ANNEX V
HAZARD PICTOGRAMS
INTRODUCTION
The hazard pictograms for each hazard class, differentiation of a hazard class and hazard category shall satisfy the provisions of this Annex and Annex I, section 1.2 and conform, in terms of colour, symbols and general format, to the specimens shown.
1. PART 1: PHYSICAL HAZARDS
1.1. Symbol: exploding bomb
Pictogram (1) | Hazard class and hazard category (2) |
GHS01 \text{Explosive, self-reactive, or organic peroxide hazard symbol} | Section 2.1 Unstable explosives Explosives of Divisions 1.1, 1.2, 1.3, 1.4 Section 2.8 Self reactive substances and mixtures, Types A, B Section 2.15 Organic peroxides, Types A, B |
1.2. Symbol: flame
Pictogram (1) | Hazard class and hazard category (2) |
GHS02 \text{flammable} | Section 2.2 Flammable gases, hazard category 1 Section 2.3 Flammable aerosols, hazard categories 1, 2 Section 2.6 Flammable liquids, hazard categories 1, 2, 3 Section 2.7 Flammable solids, hazard categories 1, 2 Section 2.8 Self-reactive substances and mixtures, Types B, C, D, E, F Section 2.9 Pyrophoric liquids, hazard category 1 Section 2.10 Pyrophoric solids, hazard category 1 Section 2.11 Self-heating substances and mixtures, hazard categories 1, 2 Section 2.12 Substances and mixtures, which in contact with water, emit flammable gases, hazard categories 1, 2, 3 Section 2.15 Organic peroxides, Types B, C, D, E, F |
1.3. Symbol: flame over circle
Pictogram (1) | Hazard class and hazard category (2) |
GHS03 I do not recognize any mathematical formula in the provided image; it is a GHS hazard pictogram for oxidizing substances. | Section 2.4 Oxidising gases, hazard category 1 Section 2.13 Oxidising liquids, hazard categories 1, 2, 3 Section 2.14 Oxidising solids, hazard categories 1, 2, 3 |
1.4. Symbol: gas cylinder
Pictogram (1) | Hazard class and hazard category (2) |
GHS04 \text{Gas cylinder symbol} | Section 2.5 Gases under pressure: Compressed gases; Liquefied gases; Refrigerated liquefied gases; Dissolved gases |
1.5. Symbol: corrosion
Pictogram (1) | Hazard class and hazard category (2) |
GHS05 \text{Corrosive hazard symbol} | Section 2.16 Corrosive to metals, hazard category 1 |
1.6. A pictogram is not required for the following physical hazard classes and hazard categories:
Section 2.1: Explosives of Division 1.5
Section 2.1: Explosives of Division 1.6
Section 2.2: Flammable gases, hazard Category 2
Section 2.8: Self-reactive substances and mixtures, Type G
Section 2.15: Organic peroxides, Type G
2. PART 2: HEALTH HAZARDS
2.1. Symbol: skull and crossbones
Pictogram (1) | Hazard class and hazard category (2) |
GHS06 \text{Toxic or hazardous substance warning symbol} | Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard categories 1, 2, 3 |
2.2. Symbol: corrosion
Pictogram (1) | Hazard class and hazard category (2) |
GHS05 \text{Corrosive hazard symbol} | Section 3.2 Skin corrosion, hazard categories 1A, 1B, 1C Section 3.3 Serious eye damage, hazard category 1 |
2.3. Symbol: exclamation mark
Pictogram (1) | Hazard class and hazard category (2) |
GHS07 \mathrm{EXCL} | Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard category 4 Section 3.2 Skin irritation, hazard category 2 Section 3.3 Eye irritation, hazard category 2 Section 3.4 Skin sensitisation, hazard category 1 Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard category 3 Respiratory tract irritation Narcotic effects |
2.4. Symbol: health hazard
Pictogram (1) | Hazard class and hazard category (2) |
GHS08 GHS08 | Section 3.4 Respiratory sensitisation, hazard category 1 Section 3.5 Germ cell mutagenicity, hazard categories 1A, 1B, 2 Section 3.6 Carcinogenicity, hazard categories 1A, 1B, 2 Section 3.7 Reproductive toxicity, hazard categories 1A, 1B, 2 Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard categories 1, 2 Section 3.9 Specific Target Organ Toxicity — Repeated exposure, hazard categories 1, 2 Section 3.10 Aspiration hazard, hazard category 1 |
2.5. A pictogram is not required for the following health hazard categories:
Section 3.7: Reproductive toxicity, Effects on or via lactation, additional hazard category
3. PART 3: ENVIRONMENTAL HAZARDS
3.1. Symbol: environment
Pictogram (1) | Hazard class and hazard category (2) |
GHS09 \text{Hazardous to the aquatic environment} | Section 4.1 Hazardous to the aquatic environment Acute hazard category 1 Chronic hazard categories 1, 2 |
A pictogram is not required for the following environmental hazard classes and hazard categories:
Section 4.1: Hazardous to the aquatic environment — Chronic hazard categories 3, 4