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New version applies from 04/07/2020. 23 provisions change. Later versions: 07/09/2020, 22/02/2021, 15/03/2021, 13/12/2022, 10/06/2023, 18/08/2023, 28/08/2023, 17/10/2024, 04/08/2025, 15/10/2025, 03/12/2025, 01/01/2026. Annex IV changes in this version: compare with the current text.

Annex IV

Annex IV

ANNEX IV

List of substances subject to waste management provisions set out in Article 7

Substance

CAS No

EC No

Concentration limit referred to in Article 7(4)(a)

Endosulfan

115-29-7 959-98-8 33213-65-9

204-079-4

50 mg/kg

Hexachlorobutadiene

87-68-3

201-765-5

100 mg/kg

Polychlorinated naphthalenes (1)

10 mg/kg

Alkanes C10-C13, chloro (short-chain chlorinated paraffins) (SCCPs)

85535-84-8

287-476-5

10 000 mg/kg

Tetrabromodiphenyl ether C12H6Br4O

40088-47-9 and others

254-787-2 and others

Sum of the concentrations of tetrabromodiphenyl ether, pentabromodiphenyl ether, hexabromodiphenyl ether, heptabromodiphenyl ether and decabromodiphenyl ether: 1 000 mg/kg. The Commission shall review that concentration limit and shall, where appropriate and in accordance with the Treaties, adopt a legislative proposal to lower that value to 500 mg/kg. The Commission shall carry out such review as soon as possible and, in any event, not later than 16 July 2021.

Pentabromodiphenyl ether C12H5Br5O

32534-81-9 and others

251-084-2 and others

Hexabromodiphenyl ether C12H4Br6O

36483-60-0 and others

253-058-6 and others

Heptabromodiphenyl ether C12H3Br7O

68928-80-3 and others

273-031-2 and others

Decabromodiphenyl ether C12Br10O

1163-19-5 and others

214-604-9 and others

Perfluorooctane sulfonic acid and its derivatives (PFOS) C8F17SO2X (X = OH, Metal salt (O-M+), halide, amide, and other derivatives including polymers)

1763-23-1 2795-39-3 29457-72-5 29081-56-9 70225-14-8 56773-42-3 251099-16-8 4151-50-2 31506-32-8 1691-99-2 24448-09-7 307-35-7 and others

217-179-8 220-527-1 249-644-6 249-415-0 274-460-8 260-375-3 223-980-3 250-665-8 216-887-4 246-262-1 206-200-6 and others

50 mg/kg

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDF)

15 μg/kg (2)

DDT (1,1,1-trichloro-2,2-bis (4-chlorophenyl)ethane)

50-29-3

200-024-3

50 mg/kg

Chlordane

57-74-9

200-349-0

50 mg/kg

Hexachlorocyclohexanes, including lindane

58-89-9 319-84-6 319-85-7 608-73-1

210-168-9 200-401-2 206-270-8 206-271-3

50 mg/kg

Dieldrin

60-57-1

200-484-5

50 mg/kg

Endrin

72-20-8

200-775-7

50 mg/kg

Heptachlor

76-44-8

200-962-3

50 mg/kg

Hexachlorobenzene

118-74-1

204-273-9

50 mg/kg

Chlordecone

143-50-0

205-601-3

50 mg/kg

Aldrin

309-00-2

206-215-8

50 mg/kg

Pentachlorobenzene

608-93-5

210-172-0

50 mg/kg

Polychlorinated Biphenyls (PCB)

1336-36-3 and others

215-648-1

50 mg/kg (3)

Mirex

2385-85-5

219-196-6

50 mg/kg

Toxaphene

8001-35-2

232-283-3

50 mg/kg

Hexabromobiphenyl

36355-01-8

252-994-2

50 mg/kg

Hexabromocyclododecane (4)

25637-99-4, 3194-55-6, 134237-50-6, 134237-51-7, 134237-52-8

247-148-4 221-695-9

1 000 mg/kg, subject to review by the Commission by 20 April 2019

(1) Polychlorinated naphthalenes means chemical compounds based on the naphthalene ring system, where one or more hydrogen atoms have been replaced by chlorine atoms.

(2) The limit is calculated as PCDD and PCDF according to the following toxic equivalency factors (TEFs):

PCDD

TEF

PCDF

TEF

PCDD

TEF

2,3,7,8-TeCDD

1

2,3,7,8-TeCDF

0,1

1,2,3,6,7,8-HxCDF

0,1

1,2,3,7,8-PeCDD

1

1,2,3,7,8-PeCDF

0,03

1,2,3,7,8,9-HxCDF

0,1

1,2,3,4,7,8-HxCDD

0,1

2,3,4,7,8-PeCDF

0,3

2,3,4,6,7,8-HxCDF

0,1

1,2,3,6,7,8-HxCDD

0,1

1,2,3,4,7,8-HxCDF

0,1

1,2,3,4,6,7,8-HpCDF

0,01

1,2,3,7,8,9-HxCDD

0,1

1,2,3,4,7,8,9-HpCDF

0,01

1,2,3,4,6,7,8-HpCDD

0,01

OCDF

0,0003

OCDD

0,0003

(3) The calculation method laid down in European standards EN 12766-1 and EN 12766-2 shall apply.

(4) ‘Hexabromocyclododecane’ means hexabromocyclododecane, 1,2,5,6,9,10-hexabromocyclododecane and its main diastereoisomers: alpha-hexabromocyclododecane, beta-hexabromocyclododecane and gamma-hexabromocyclododecane.

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